01. It's Dejiko-nyo!
Dejiko (Digi Charat), Puchiko (Petit Charat) and Gema are heading for Earth in their cat shaped UFO, in order to complete Dejiko's "princess training", but because of an explosion, Puchiko is blown outside the ship.
02. Together With Puchiko-nyo?
After they manage to land safely on Earth, Dejiko and Gema search for Puchiko and find her inside a toy department.
03. The Riddle Cell Phone-nyo
Dejiko is trying to find her white, cat-face shaped pochette, in which she had her cellphone.
04. I Won't Call You Rabi~En~Rose-nyo
Dejiko and Puchiko meet a junior high girl, Usada Hikaru, that insists to be called Rabi-en-Rose.
05. Baked Puchiko is Delicious-nyu
Dejiko and Puchiko become popular after making cakes called "Puchikos" that look just like Puchiko's pochette.
06. Dejiko is a Princess-nyo
Gema tells everybody about how life was on Planet Di Gi Charat, the home planet of Dejiko and Puchiko.
07. A Splendid Day for Usada-nyo
Rabi-en-Rose wants to enter an idol competition.
08. A Public Bath Called "Daily Hot Water"-nyo
Because of a new green bath toy that grows when wet is occupying the bathroom, Dejiko and the others decide to go to a public bath.
09. Usada's Bo-Bo School -nyo!
At school, Hikaru notices that Kyoshi has forgotten his lunch at home, and tries to get a "date" with him, offering him to share her lunch. However, Digiko and Puchiko are on their way to school bringing Kyoshi his lunch.
10. Nazo no Omise ni Otsukai nyo
Digiko, Puchiko and Genma go shopping and end up inside a weird store where the cashier is a man with a jack o'lantern for a head.
11. Ayatori Meijinsen nyo
Puchiko leaves on a quest to find some "nattou" (fermented soybeans), while Gema and Daifuku confront each other in an "ayatori" (string tricks) contest.
12. Amaenbou da nyo
A young boy called Amaenbou who loves sweets and pulling on Digiko's tail starts following Digiko and Puchiko around everywhere they go.
13. Shoutengai de Oouridashi nyo
At a special town meeting, it is decided that they should ask Akari Usada to have a concert there. The entire Neko Maneki Shopping Center prepares for the celebration.
14. Oouridashi de Kayou Show nyo
On the day of the big celebration, Digiko and Puchiko try to get inside Akari's trailer, to talk to their idol.
15. Itokono Neechan ka nyo
Rabi en Rose tells a story about how she and Akari were friends a long time ago before she became an idol.
16. Digiko Megane ha Kowai nyo
Everybody in town starts wearing special glasses that makes them look like Digiko, just to annoy her.
17. Digiko no Wagashizukuri nyo
When Daifuku and Kinako leave on vacation, Digiko is left in charge of the bakery and has to make a cake for a client.
18. Kiyoshi, You're Great-nyo!
Kiyoshi starts developing super powers and accidentally destroys the school.
19. Derorin Chirorin nyo
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20. Himashiyu kara waita nyo
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21. Manmaru Jinja no ikimono nyo
Digiko and Puchiko follow Hikaru to a shrine to see what she's doing. There they meet her best friend, Majingabbo, a water demon.
22. Kowai Picnic nyo
Digiko and the others go on a picnic, but they get lost in the forest and meet a giant who wants to eat them.
23. Shoutengai ni terebi ga kita nyo
A documentary about the Neko Maneki Shopping Center is being filmed, and Digiko and the others are cast as actors.
24. Puchiko ranking happyou nyu
Digiko and the others hold a party for Puchiko, where they ask her to name her favorite persons.
25. Princess shugyou ha ii choushi nyo
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26. Are You Homesick-nyo?
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27. Rabi-en tanjou no Himitsu
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28. Mekara Beam wo dasanai nyo
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29. Akihabara ni Otsukai nyo
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30. Korega Manatsu no Akihabara nyo
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31. Linna? Daredesitaka nyo
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32. Linna Nemurimakuri nyo
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33. Natsumatsuri ga yattekuru nyo
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34. Iyoiyo Natsumatsuri nyo
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35. Kowai Hanashi nyo
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36. Ujaja kan no Yuurei-chan nyo
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37. Aqua-chan ga Tsureta nyo
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38. Umi de Koi no Natsu! Sugu-n Gema
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39. Digiko, Eiga ni Shutsuen suru nyo
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40. Akari to Kyouen suru nyo
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41. Sashisuseso ga Umareta nyo
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42. Digiko Furima ni Chousen nyo
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43. Digiko wo Mamoru Knight da nyo
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44. Kaasama ga kita nyo
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45. Uchuujin Shuurai nyo
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46. Puchiko Shiawase wo Sagasu nyu
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47. Mike to Deka zakana Arawareta nyo
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48. Densetsu no Sao ga Hoshii nyo
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49. Kinoko gari ha Tanoshii nyo
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50. Omochan ga Nakunaru nyo
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51. Magikano Misuteki Tour nyo
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52. Digiko Kaeru nyo
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53. Piyoko ha Aku no Shuryou nyo
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54. Ryakushite Bugedan nyo
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55. Kareida-san ga Kuru nyo
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56. Kareida-san pinch nyo
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57. Dejiko is Number One-nyo!
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58. Mekara Beam ha Akogare nyu
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59. Nanikaya de arubaito nyo
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60. Yasushi tai Riku nazo no taiketsu nyo
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61. Shouwakusei ga Gekitotsu nyo!
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62. Digiko no Warashibe chouja nyo
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63. Gosenzo-sama ga yattekita nyo
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64. Digiko kira kira nyo
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65. Bugedan Puchiko wo Nerau nyo
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66. Bugedan Usada wo Naerau nyo
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67. Piyoko no Gokuaku Item nyo
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68. DiGi Charat to ha nandesuka
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69. Kiyoshi wo Sagasu nyo
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70. Warui Yokan ni goshoutai nyo
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71. Fushigi no Kuni no Usamimi-chan
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72. Digiko mo Usamimi Hoshii nyo
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73. Nenmatsu Akihabara ni Iku nyo
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74. Akihabara 7 nin Musume nyo
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75. Shoutengai mo Christmas nyo
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76. Santa-san no Otetudai nyo
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77. Let's Find the Golden Door -nyo!
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78. Can We Really Find the Golden Door -nyo?
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79. The Princess School -nyo!
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80. Usada, the Bo-Bo Princess -nyo!
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81. Kyuushoku ha Uresii nyo
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82. Puri Puri Bu- Kessei yo
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83. Kagai Jugyou ni Odekake nyo
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84. Princess kun Toujousa!
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85. The Costumes Store -nyo!
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86. I Need to Act as a Princess -nyo!
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87. An Elegant Lesson -nyo!
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88. The Princesses' Music Group is Born -nyo!
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89. Rod P Shishakai Akihabara nyo
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90. Kuma King Ge Dan Akihabara nyo
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91. Valentine no Choco wo Mamoru nyo
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92. Fushigi-kun ni Arigato nyo
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93. Akari no Shigotoba ni iku nyo
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94. Yukiyama de Yahhohho- nyo
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95. Princess Tenkousei ga Kuru nyo
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96. Me kara Beam ha Oshimaika nyo?
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97. Kaeri Michi de Yori Michi nyo
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98. Digiko no Karei na Tabi nyo
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99. Princess School Seven Wonders-nyo
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100. Shoutengai ni Princess School nyo
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101. Chotto dake Oneesan kibun nyo
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102. Digiko no Sakubun Happyou nyo
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103. Princess School Festival-nyo
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104. Di Gi Charat Returns to the Planet-nyo
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